Unknown

Dataset Information

0

6-[(Dimethyl-amino)methyl-ene-amino]-1,3-dimethyl-pyrimidine-2,4(1H,3H)-dione dihydrate.

ABSTRACT: Uracil, the pyrimidine nucleobase, which combined with adenine forms one of the major motifs present in the biopolymer RNA, is also involved in the self-assembly of RNA. In the title compound, C(9)H(14)N(4)O(2)·2H(2)O, the asymmetric unit contains one dimethyl-amino-uracil group and two water mol-ecules. The plane of the N=C-NMe(2) side chain is inclined at 27.6?(5)° to the plane of the uracil ring. Both water mol-ecules form O-H?O hydrogen bonds with the carbonyl O atoms of the uracil group. Additional water-water hydrogen-bond inter-actions are also observed in the crystal structure. The O-H?O hydrogen bonds lead to the formation of a two-dimensional hydrogen-bonded network cage consisting of two dimethyl-amino-uracil groups and six water mol-ecules.

SUBMITTER: Das S 

PROVIDER: S-EPMC2960636 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

6-[(Dimethyl-amino)methyl-ene-amino]-1,3-dimethyl-pyrimidine-2,4(1H,3H)-dione dihydrate.

Das Subrata S   Saikia Binoy K BK   Sridhar B B   Thakur Ashim J AJ  

Acta crystallographica. Section E, Structure reports online 20080806 Pt 9

Uracil, the pyrimidine nucleobase, which combined with adenine forms one of the major motifs present in the biopolymer RNA, is also involved in the self-assembly of RNA. In the title compound, C(9)H(14)N(4)O(2)·2H(2)O, the asymmetric unit contains one dimethyl-amino-uracil group and two water mol-ecules. The plane of the N=C-NMe(2) side chain is inclined at 27.6 (5)° to the plane of the uracil ring. Both water mol-ecules form O-H⋯O hydrogen bonds with the carbonyl O atoms of the uracil group. Ad  ...[more]

Similar Datasets

Unknown (E)-6-Amino-1,3-dimethyl-5-[(pyridin-2-yl-methyl-idene)amino]-pyrimidine-2,4(1H,3H)-dione.
| S-EPMC3200715 | biostudies-literature
Unknown 6-Amino-1,3-dimethyl-5-[(E)-2-(methyl-sulfan-yl)benzyl-idene-amino]-pyrimidine-2,4(1H,3H)-dione.
| S-EPMC3151916 | biostudies-literature
Unknown A second monoclinic polymorph of 6-amino-1,3-dimethyl-5-[(E)-2-(methyl-sulfan-yl)benzyl-idene-amino]-pyrimidine-2,4(1H,3H)-dione.
| S-EPMC3213476 | biostudies-literature
Unknown 1,3-Dimethyl-3-tetra-decyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione.
| S-EPMC3052003 | biostudies-literature
Unknown 3,8-Dimethyl-quinazoline-2,4(1H,3H)-dione.
| S-EPMC3212315 | biostudies-literature
Unknown 5-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra-hydropyrimidin-5-yl)-1,3-dimethyl-1H-chromeno[2,3-d]pyrim-idine-2,4(3H,5H)-dione 3.5-hydrate.
| S-EPMC3685110 | biostudies-literature
Unknown 7-(Benzyl-sulfan-yl)-5-(2-methoxy-phen-yl)-1,3-dimethyl-5,6-dihydro-pyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione.
| S-EPMC2960738 | biostudies-literature
Unknown 5-Fluoro-1-(penta-noyl)pyrimidine-2,4(1H,3H)-dione.
| S-EPMC2960789 | biostudies-literature
Unknown 6-(Trifluoro-meth-yl)pyrimidine-2,4(1H,3H)-dione monohydrate.
| S-EPMC3006960 | biostudies-literature
Unknown 1,3-Bis(4-methyl-benz-yl)pyrimidine-2,4(1H,3H)-dione.
| S-EPMC2980275 | biostudies-other