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Poly[[bis(?(2)-4-amino-benzene-sul-fon-ato-?N:O)diaqua-manganese(II)] dihydrate].

ABSTRACT: The title compound, {[Mn(NH(2)C(6)H(4)SO(3))(2)(H(2)O)(2)]·2H(2)O}(n), was prepared under mild hydro-thermal conditions. The unique Mn(II) ion is located on a crystallographic inversion center and is coordinated by two -NH(2) and two -SO(3) groups from four 4-amino-benzene-sulfonate ligands and by two water mol-ecules in the axial positions, forming a slightly distorted octa-hedral coordination environment. The 4-amino-benzene-sulfonate anions behave as ?(2)-bridging ligands to produce a two-dimensional structure. In the crystal structure, inter-molecular N-H?O, O-H?O and C-H?O hydrogen bonds link the layers into a three-dimensional network.

SUBMITTER: Li ZL

PROVIDER: S-EPMC2960641 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Poly[[bis(μ(2)-4-amino-benzene-sul-fon-ato-κN:O)diaqua-manganese(II)] dihydrate].

Li Zhan Ling ZL Xuan Ya Wen YW Wu Wen W Xie Dong Po DP

Acta crystallographica. Section E, Structure reports online 20080813 Pt 9

The title compound, {[Mn(NH(2)C(6)H(4)SO(3))(2)(H(2)O)(2)]·2H(2)O}(n), was prepared under mild hydro-thermal conditions. The unique Mn(II) ion is located on a crystallographic inversion center and is coordinated by two -NH(2) and two -SO(3) groups from four 4-amino-benzene-sulfonate ligands and by two water mol-ecules in the axial positions, forming a slightly distorted octa-hedral coordination environment. The 4-amino-benzene-sulfonate anions behave as μ(2)-bridging ligands to produce a two-dim ...[more]

PMID: 21201611

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