Unknown

Dataset Information

0

Poly[[bis(?(2)-4-amino-benzene-sul-fon-ato-?N:O)diaqua-manganese(II)] dihydrate].

ABSTRACT: The title compound, {[Mn(NH(2)C(6)H(4)SO(3))(2)(H(2)O)(2)]·2H(2)O}(n), was prepared under mild hydro-thermal conditions. The unique Mn(II) ion is located on a crystallographic inversion center and is coordinated by two -NH(2) and two -SO(3) groups from four 4-amino-benzene-sulfonate ligands and by two water mol-ecules in the axial positions, forming a slightly distorted octa-hedral coordination environment. The 4-amino-benzene-sulfonate anions behave as ?(2)-bridging ligands to produce a two-dimensional structure. In the crystal structure, inter-molecular N-H?O, O-H?O and C-H?O hydrogen bonds link the layers into a three-dimensional network.

SUBMITTER: Li ZL 

PROVIDER: S-EPMC2960641 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Poly[[bis(μ(2)-4-amino-benzene-sul-fon-ato-κN:O)diaqua-manganese(II)] dihydrate].

Li Zhan Ling ZL   Xuan Ya Wen YW   Wu Wen W   Xie Dong Po DP  

Acta crystallographica. Section E, Structure reports online 20080813 Pt 9

The title compound, {[Mn(NH(2)C(6)H(4)SO(3))(2)(H(2)O)(2)]·2H(2)O}(n), was prepared under mild hydro-thermal conditions. The unique Mn(II) ion is located on a crystallographic inversion center and is coordinated by two -NH(2) and two -SO(3) groups from four 4-amino-benzene-sulfonate ligands and by two water mol-ecules in the axial positions, forming a slightly distorted octa-hedral coordination environment. The 4-amino-benzene-sulfonate anions behave as μ(2)-bridging ligands to produce a two-dim  ...[more]

Similar Datasets

Unknown Poly[[hexa-?-aqua-diaqua-bis-(??-dihydrogen benzene-1,2,4,5-tetra-carboxyl-ato)magnesiumdisodium] dihydrate].
| S-EPMC3393174 | biostudies-literature
Unknown catena-Poly[[[diaqua-bis[4-(diethyl-amino)benzoato-?O]manganese(II)]-?-aqua] dihydrate].
| S-EPMC2969307 | biostudies-literature
Unknown Diaqua-bis(pyrazine-2-carboxyl-ato-?N,O)manganese(II) dihydrate.
| S-EPMC2961000 | biostudies-literature
Unknown catena-Poly[[[diaqua-(1,3-benzimidazole-κN)manganese(II)]-μ-benzene-1,3-di-carboxyl-ato-κO,O:O] dihydrate].
| S-EPMC3099958 | biostudies-literature
Unknown catena-Poly[bis-(4-amino-pyridinium) [[tetra-aqua-nickel(II)]-?-benzene-1,2,4,5-tetra-carboxyl-ato] dihydrate].
| S-EPMC2970276 | biostudies-literature
Unknown Poly[octa-μ-aqua-tetra-aqua-bis(μ-5-sul-fon-atobenzene-1,3-dicarboxyl-ato)cobalt(II)tetra-sodium].
| S-EPMC2968916 | biostudies-literature
Unknown Bis(4-amino-benzene-sulfonato-?N)diaqua-bis(dimethyl-formamide-?O)nickel(II) dihydrate.
| S-EPMC2969510 | biostudies-literature
Unknown Bis(3-amino-pyrazine-2-carboxyl-ato-?N,O)diaqua-manganese(II).
| S-EPMC2983285 | biostudies-literature
Unknown catena-Poly[[[diaqua-manganese(II)]-?(3)-pyridine-2,3-dicarboxyl-ato-?N,O:O:O] dihydrate].
| S-EPMC2959413 | biostudies-literature
Unknown Poly[[diaqua-bis-(μ(3)-3-carboxyl-ato-4-hy-droxy-benzene-sulfonato)-tri-μ(2)-pyrazine-tetra-silver(I)] dihydrate].
| S-EPMC3246968 | biostudies-literature