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Bis(?-biphenyl-2,2'-dicarboxyl-ato)bis-[(2,2'-bipyridine)copper(II)].

ABSTRACT: The title compound, [Cu(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear copper(II) complex, with a Cu?Cu separation of 6.136?(16)?Å. The Cu atom displays a cis-CuN(2)O(2) square-planar geometry, although two long (> 2.43?Å) Cu?O contacts complete a distorted cis-CuN(2)O(4) octa-hedron. Extensive C-H?O hydrogen bonds link the mol-ecules into a three-dimensional network.

SUBMITTER: Guo HX 

PROVIDER: S-EPMC2960666 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Bis(μ-biphenyl-2,2'-dicarboxyl-ato)bis-[(2,2'-bipyridine)copper(II)].

Guo Hong-Xu HX   Liang Min M   Lin Bin B   Wang Qing-Hua QH   Li Xi-Zhong XZ  

Acta crystallographica. Section E, Structure reports online 20080816 Pt 9

The title compound, [Cu(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear copper(II) complex, with a Cu⋯Cu separation of 6.136 (16) Å. The Cu atom displays a cis-CuN(2)O(2) square-planar geometry, although two long (> 2.43 Å) Cu⋯O contacts complete a distorted cis-CuN(2)O(4) octa-hedron. Extensive C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. ...[more]

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