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Hexaaqua-zinc(II) dichloride bis-(hexa-methyl-enetetramine) tetra-hydrate.

ABSTRACT: The title compound, [Zn(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, has been prepared under mild hydro-thermal conditions. The Zn(II) atom, located on a centre of symmetry, is coordinated by six water mol-ecules in a distorted octa-hedral coordination geometry. The hexa-methyl-enetetra-mine mol-ecule is not coordinated to Zn(II) but links the Zn complexes via three O-H?N hydrogen bonds. The remaining N atom of the hexa-methyl-enetetra-mine mol-ecule is hydrogen-bonded to a solvent water mol-ecule. In the crystal structure, inter-molecular O-H?O, O-H?N and O-H?Cl hydrogen bonds link the components into a three-dimensional network.

SUBMITTER: Yao XJ

PROVIDER: S-EPMC2960671 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Hexaaqua-zinc(II) dichloride bis-(hexa-methyl-enetetramine) tetra-hydrate.

Yao Xin Jian XJ Xuan Ya Wen YW Wu Wen W

Acta crystallographica. Section E, Structure reports online 20080806 Pt 9

The title compound, [Zn(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, has been prepared under mild hydro-thermal conditions. The Zn(II) atom, located on a centre of symmetry, is coordinated by six water mol-ecules in a distorted octa-hedral coordination geometry. The hexa-methyl-enetetra-mine mol-ecule is not coordinated to Zn(II) but links the Zn complexes via three O-H⋯N hydrogen bonds. The remaining N atom of the hexa-methyl-enetetra-mine mol-ecule is hydrogen-bonded to a solvent water mol-ecule. In ...[more]

PMID: 21201590

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