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2,2'-Dimethoxy-biphen-yl.


ABSTRACT: The mol-ecule of the title compound, C(14)H(14)O(2), lies on a crystallographic twofold axis perpendicular to the central C-C bond; there is one half-mol-ecule in the asymmetric unit. The angle between the least-squares planes of the two aromatic rings is 66.94?(7)°. The meth-oxy group, with a twist angle of 10.69?(8)°, is slightly out of the plane of the benzene ring. In the crystal structure, C-H?? inter-actions are observed between adjacent mol-ecules along the c-axis direction.

SUBMITTER: Nakaema K 

PROVIDER: S-EPMC2960700 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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2,2'-Dimethoxy-biphen-yl.

Nakaema Kosuke K   Okamoto Akiko A   Maruyama Satoshi S   Noguchi Keiichi K   Yonezawa Noriyuki N  

Acta crystallographica. Section E, Structure reports online 20080809 Pt 9


The mol-ecule of the title compound, C(14)H(14)O(2), lies on a crystallographic twofold axis perpendicular to the central C-C bond; there is one half-mol-ecule in the asymmetric unit. The angle between the least-squares planes of the two aromatic rings is 66.94 (7)°. The meth-oxy group, with a twist angle of 10.69 (8)°, is slightly out of the plane of the benzene ring. In the crystal structure, C-H⋯π inter-actions are observed between adjacent mol-ecules along the c-axis direction. ...[more]

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