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Catena-Poly[[(2-{1-[2-(2-amino-ethyl-amino)ethyl-imino]-eth-yl}-5-methoxy-phenolato-?N,N',N'',O)copper(II)]-?-nitrato-?O:O'].

ABSTRACT: In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04?Å). The complex mol-ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu-O bonds of 2.535?(6) and 2.676?(7)?Å, completing a distorted octa-hedral coordination geometry. The NH groups of the ligand form hydrogen bonds to the nitrate anions.

SUBMITTER: Wang S

PROVIDER: S-EPMC2960731 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[(2-{1-[2-(2-amino-ethyl-amino)ethyl-imino]-eth-yl}-5-methoxy-phenolato-κN,N',N'',O)copper(II)]-μ-nitrato-κO:O'].

Wang Suwen S Li Zhongfang Z Wang Xutao X Yu Xianjin X

Acta crystallographica. Section E, Structure reports online 20080723 Pt 9

In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol-ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu-O bonds of 2.535 (6) and 2.676 (7) Å, completing a distorted octa-hedral coordination geometry. The NH groups of the ligand form hydrogen bonds to the nitrate anions. ...[more]

PMID: 21201632

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