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Catena-Poly[[[?-cyanido-1:2?C:N-tricyanido-1?C-bis(ethylenediamine)-2?N,N'-copper(II)iron(II)]-?-cyanido-?C:N-[bis(ethylenediamine-?N,N')copper(II)]-?-cyanido-?N:C] 4.5-hy-drate].

ABSTRACT: The asymmetric unit of the title compound, {[Cu(2)Fe(CN)(6)(C(2)H(8)N(2))(4)]·4.5H(2)O}(n), consists of two [Cu(C(2)H(8)N(2))(2)](2+) cations, one [Fe(CN)(6)](4-) anion, four water mol-ecules and a half water mol-ecule that lies on a twofold rotation axis. The Fe(II) atom is coordinated by six C atoms from three terminal and three doubly bridging CN(-) ligands. The bridging CN(-) ligands connect the anion to a five-coordinate [Cu(C(2)H(8)N(2))(2)](2+) cation and to two symmetry-related six-coordinate [Cu(C(2)H(8)N(2))(2)](2+) cations, forming a one-dimensional polymer in the ab plane. Inter-molecular hydrogen bonds connect the polymer units into a three-dimensional network.

SUBMITTER: Liu H

PROVIDER: S-EPMC2960737 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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catena-Poly[[[μ-cyanido-1:2κC:N-tricyanido-1κC-bis(ethylenediamine)-2κN,N'-copper(II)iron(II)]-μ-cyanido-κC:N-[bis(ethylenediamine-κN,N')copper(II)]-μ-cyanido-κN:C] 4.5-hy-drate].

Liu Hongling H Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20080809 Pt 9

The asymmetric unit of the title compound, {[Cu(2)Fe(CN)(6)(C(2)H(8)N(2))(4)]·4.5H(2)O}(n), consists of two [Cu(C(2)H(8)N(2))(2)](2+) cations, one [Fe(CN)(6)](4-) anion, four water mol-ecules and a half water mol-ecule that lies on a twofold rotation axis. The Fe(II) atom is coordinated by six C atoms from three terminal and three doubly bridging CN(-) ligands. The bridging CN(-) ligands connect the anion to a five-coordinate [Cu(C(2)H(8)N(2))(2)](2+) cation and to two symmetry-related six-coord ...[more]

PMID: 21201602

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