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Trans-Carbonyl-chloridobis(tri-p-tolyl-phosphine)rhodium(I) acetone solvate.

ABSTRACT: The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d(6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris-(hydroxy-meth-yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo-octa-diene]. The complex displays a square-planar geometry around the Rh(I) atom. The complex mol-ecules and the acetone mol-ecules are linked into a chain along the a axis by inter-molecular C-H?Cl and C-H?O hydrogen bonds.

SUBMITTER: Lorenzini F

PROVIDER: S-EPMC2960764 | biostudies-literature | 2008 Feb

REPOSITORIES: biostudies-literature

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trans-Carbonyl-chloridobis(tri-p-tolyl-phosphine)rhodium(I) acetone solvate.

Lorenzini Fabio F Patrick Brian O BO James Brian R BR

Acta crystallographica. Section E, Structure reports online 20080208 Pt 3

The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d(6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris-(hydroxy-meth-yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo-octa-diene]. The complex displays a square-planar geometry around the Rh(I) atom. The complex mol-ecules and the acetone mol-ecules are linked into a chain along the a axis by inter-molecular C-H⋯Cl a ...[more]

PMID: 21201856

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