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Catena-Poly[[silver(I)-?-[N-(4-pyridyl-meth-yl)pyridine-4-carboxamide-?N:N']] nitrate monohydrate].


ABSTRACT: The title coordination polymer, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), has a polycationic chain motif in which the Ag atom is bridged by the heterocyclic ligand; the Ag atom shows linear coordination. If the two long Ag?O(nitrate) inter-actions [2.794?(6) and 2.867?(5)?Å] are regarded as bonds, the compound adopts a three-dimensional network structure. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion.

SUBMITTER: Ma YT 

PROVIDER: S-EPMC2960773 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

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catena-Poly[[silver(I)-μ-[N-(4-pyridyl-meth-yl)pyridine-4-carboxamide-κN:N']] nitrate monohydrate].

Ma Yu-Tao YT   Sun Bai-Wang BW   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20080213 Pt 3


The title coordination polymer, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), has a polycationic chain motif in which the Ag atom is bridged by the heterocyclic ligand; the Ag atom shows linear coordination. If the two long Ag⋯O(nitrate) inter-actions [2.794 (6) and 2.867 (5) Å] are regarded as bonds, the compound adopts a three-dimensional network structure. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion. ...[more]

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