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(1R,2R)-4-Benzoyl-2-benzo-yloxy-1-phenyl-butyl imidazole-1-carboxyl-ate.

ABSTRACT: The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenyl-propane-1,3-dione using standard Sharpless asymmetric dihydroxy-lation conditions, followed by treatment with 1,1'-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter-molecular face-to-face ?-? contacts, with an inter-planar angle of 15.5?(2)° and a centroid-centroid distance of 4.73?(1)?Å. One phenyl ring also forms a C-H?? contact to an adjacent imidazole ring, with an H?centroid distance of 3.18?Å.

SUBMITTER: Fox DJ

PROVIDER: S-EPMC2960783 | biostudies-literature |

REPOSITORIES: biostudies-literature

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