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2,6-Di-tert-butyl-4-(methoxy-meth-yl)phenol.

ABSTRACT: The title compound, C(16)H(26)O(2), was easily obtained in high yield when 4-bromo-methyl-2,6-di-tert-butyl-phenol was reacted with methanol. There are two independent mol-ecules in the asymmetric unit. The meth-oxy group in each of the independent mol-ecules was found to be disordered, with site-occupation factors of 0.8728?(18)/0.1272?(18) and 0.8781?(17)/0.1219?(17).

SUBMITTER: Zeng T

PROVIDER: S-EPMC2960792 | biostudies-literature |

REPOSITORIES: biostudies-literature

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2,6-Di-tert-butyl-4-(dimethyl-amino-meth-yl)phenol.

Project description:The title compound, C(17)H(29)NO, is an important hindered phenol derivative. The asymmetric unit contains two mol-ecules. Molecules inter-act through O-H?N hydrogen bonds to form a tetramer arranged around a twofold rotation axis.

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2,6-Di-tert-butyl-4-[(N-methyl-anilino)meth-yl]phenol.

Project description:The title compound, C(22)H(31)NO, has been synthesized from 4-bromo-methyl-2,6-di-tert-butyl-phenol and N-methyl-aniline. There are two independent mol-ecules in the asymmetric unit. The aniline ring in each of the independent mol-ecules was found to be disordered, with site occupation factors 0.621?(10)/0.379?(10) and 0.605?(10)/0.395?(10).

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2,6-Di-tert-butyl-4-(morpholinometh-yl)-phenol monohydrate.

Project description:In the title compound, C(19)H(31)NO(2)·H(2)O, the morpholine ring adopts a chair conformation, while the phenolic hydroxyl group is sterically hindered by the adjacent tert-butyl groups. The crystal structure is stabilized by a number of O-H?O, O-H?N and C-H?O hydrogen-bonding inter-actions, involving both the organic and the solvent mol-ecules.

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Di-tert-butyl N-[2,6-bis-(methoxy-meth-oxy)phen-yl]imino-diacetate.

Project description:The title mol-ecule, C(20)H(31)NO(8), has pseudo-C2 symmetry about the C-N bond, with the bis-(tert-butoxy-carbon-yl)amino group twisted from the benzene ring plane by ca 60° and the bulky tert-butoxy-carbonyl (Boc) groups are orientated away from the substituted aniline group. As part of an anti-bacterial drug discovery programme furnishing analogues of platensimycin, we unexpectedly synthesized the bis-Boc-protected aniline.

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2,6-Di-tert-butyl-4-(3-chloro-2-hy-droxy-prop-yl)phenol.

Project description:In the title 2-propanol derivative, C(17)H(27)ClO(2), the two tert-butyl groups both have one methyl C atom lying in the plane of the aromatic ring. In the crystal, the phenol group forms a hydrogen bond to the hy-droxy O atom belonging to the alkyl substituent of an adjacent mol-ecule, forming a chain along the ac diagonal. The Cl atom is disordered over two positions in a 0.73?(4):0.27?(4) ratio.

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Crystal structure of (<i>E</i>)-2,6-di-<i>tert</i>-butyl-4-{[2-(2,4-di-nitro-phen-yl)hydrazinylidene]meth-yl}phenol.

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(E)-2-[(2-Amino-phen-yl)imino-meth-yl]-4,6-di-tert-butyl-phenol.

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(E)-2-{[(2-Amino-pyridin-3-yl)imino]-meth-yl}-4,6-di-tert-butyl-phenol.

Project description:In the title compound, C(20)H(27)N(3)O, the hy-droxy group forms an intra-molecular O-H⋯N hydrogen bond with the imino N atom. The dihedral angle between the aromatic rings is 33.09 (9)°. In the crystal, mol-ecules form centrosymmetric dimers via pairs of N-H⋯N hydrogen bonds involving amino-pyridine fragments.

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