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Diaqua-bis(4-chloro-benzoato-?O)bis-(N,N-diethyl-nicotinamide-?N)manganese(II).

ABSTRACT: The title compound, [Mn(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Mn(II) atom lying on an inversion center. It contains two 4-chloro-benzoate and two diethyl-nicotinamide ligands and two water mol-ecules, all of which are monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octa-hedral geometry is completed by two N atoms in the axial positions. In the crystal structure, O-H?O hydrogen bonds link the mol-ecules into an infinite chain.

SUBMITTER: Hokelek T

PROVIDER: S-EPMC2960864 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

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Diaqua-bis(4-chloro-benzoato-κO)bis-(N,N-diethyl-nicotinamide-κN)manganese(II).

Hökelek Tuncer T Caylak Nagihan N Necefoğlu Hacali H

Acta crystallographica. Section E, Structure reports online 20080229 Pt 3

The title compound, [Mn(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Mn(II) atom lying on an inversion center. It contains two 4-chloro-benzoate and two diethyl-nicotinamide ligands and two water mol-ecules, all of which are monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octa-hedral geometry is completed by two N atoms in the axial positions. In the crystal str ...[more]

PMID: 21201885

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