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6-Meth-oxy-2,3,4,9-tetra-hydro-1H-carbazol-1-one.

ABSTRACT: The carbazole unit of the title mol-ecule, C(13)H(13)NO(2), is not planar. The dihedral angle between the benzene ring and the pyrrole ring is 1.69 (6)°. The cyclo-hexene ring adopts an envelope conformation. Inter-molecular C-H⋯O and N-H⋯O hydrogen bonds are present in the crystal structure. A C-H⋯π inter-action, involving the benzene ring, is also found in the crystal structure.

SUBMITTER: Sridharan M

PROVIDER: S-EPMC2960955 | biostudies-literature |

REPOSITORIES: biostudies-literature

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8-Methyl-2,3,4,9-tetra-hydro-1H-carbazol-1-one.

Project description:In the title compound, C(13)H(13)NO, the dihedral angle between the benzene ring and the fused pyrrole ring is 0.96 (7)°. The cyclohexenone ring adopts an envelope conformation. Inter-molecular N-H⋯O hydrogen bonds form R(2) (2)(10) ring motifs in the crystal structure. Weak C-H⋯π inter-actions involving the benzene ring also occur.

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Project description:In the title compound, C17H24N2O5S2, the indole ring system is nearly planar [maximum deviation = 0.032?(1)?Å] and the cyclo-hexene ring has a half-chair conformation. In the crystal, N-H?O hydrogen bonds link the mol-ecules into a chain running along the b-axis direction. Weak C-H?O hydrogen bonds and weak C-H?? inter-actions are observed between the chains.

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(E)-2-[(Furan-2-yl)methyl-idene]-7-methyl-2,3,4,9-tetra-hydro-1H-carbazol-1-one.

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Project description:In the title compound, C(17)H(12)BrNOS, the cyclo-hexene ring deviates only slightly from planarity (r.m.s. deviation for non-H atoms = 0.047 Å). In the crystal, the mol-ecules are linked into centro-symmetric R(2) (2)(10) dimers via pairs of N-H⋯O hydrogen bonds. The thio-phene ring is disordered over two positions rotated by 180° and with a site-occupation factor of 0.843 (4) for the major occupied site.

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