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Di-μ-chlorido-bis-[bis-(η-cyclo-octene)iridium(I)].

ABSTRACT: The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.

SUBMITTER: Yamagata T

PROVIDER: S-EPMC2960958 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-[bis-(η-cyclo-octene)iridium(I)].

Yamagata Tsuneaki T Nakajima Koji K Arimitsu Kenji K Iseki Aika A Tani Kazuhide K

Acta crystallographica. Section E, Structure reports online 20080329 Pt 4

The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar. ...[more]

PMID: 21202029

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