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Iodidotris(triphenyl-phosphine)copper(I) acetonitrile solvate.

ABSTRACT: The title compound, [CuI(C(18)H(15)P)(3)]·C(2)H(3)N, was obtained from the reaction of triphenyl-phosphine and copper(I) iodide in acetonitrile. The monomeric form of the complex has slightly distorted coordination of Cu by the I atom and three P atoms. The crystal structure is stabilized by C-H⋯π inter-actions between phenyl H atoms and phenyl rings. In addition, the complex mol-ecules exhibit C-H⋯N hydrogen bonds between phenyl H atoms and acetonitrile N atoms. The crystal used was an inversion twin, with nearly equal component populations of 0.522 (8) and 0.478 (8).

SUBMITTER: Venkatraman R

PROVIDER: S-EPMC2960968 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Nitratotris(triphenyl-phosphine)copper(I) methanol solvate.

Project description:The title compound, [Cu(NO(3))(C(18)H(15)P)(3)]·CH(3)OH, is a methanol solvate derivative of nitratotris(triphenyl-phos-phine)copper(I). The complex crystallizes with three triphenyl-phosphine ligands coordinated to the copper centre, with an O-H?O hydrogen bond observed between the nitrate ligand and the methanol solvent mol-ecule. The coordination around the Cu(I) centre is distorted tetrahedral.

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Poly[[(?(3)-isonicotinato-?O:O:N)(triphenyl-phosphine-?P)silver(I)] ethanol solvate].

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Project description:The coordination geometry of the Cu atom in the title compound, [CuI(C(7)H(8)N(2)S)(C(18)H(15)P)(2)], is distorted tetra-hedral; it is coordinated by two triphenyl-phosphine P atoms, one S atom from N-phenyl-thio-urea (ptu) and one I atom. The crystal structure is stabilized by intra- and inter-molecular N-H⋯I and N-H⋯S inter-actions.

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(Benzophenone imine-κN)-chlorido(hydrido-tripyrazolyl-borato)-(triphenyl-phosphine)ruthenium(II) diethyl ether solvate.

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