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[2-(2-Carboxy-phen-yl)benzoato]bis-(1,10-phenanthroline)zinc(II) 2-(2-carboxy-phen-yl)benzoate monohydrate.

ABSTRACT: In the title compound, [Zn(C(14)H(9)O(4))(C(12)H(8)N(2))(2)](C(14)H(9)O(4))·H(2)O, the Zn(II) atom of the complex cation is six-coordinated in an octa-hedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxyl-ate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05?(2) (ligand) and 89.10?(2)° (anion). O-H?O and C-H?O hydrogen bonds link the components into a three-dimensional network.

SUBMITTER: Huang WW 

PROVIDER: S-EPMC2961034 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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[2-(2-Carboxy-phen-yl)benzoato]bis-(1,10-phenanthroline)zinc(II) 2-(2-carboxy-phen-yl)benzoate monohydrate.

Huang Wei-Wei WW   Yang Shi-Ping SP  

Acta crystallographica. Section E, Structure reports online 20080307 Pt 4

In the title compound, [Zn(C(14)H(9)O(4))(C(12)H(8)N(2))(2)](C(14)H(9)O(4))·H(2)O, the Zn(II) atom of the complex cation is six-coordinated in an octa-hedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxyl-ate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)°  ...[more]

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