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Hexakis(1H-imidazole-?N)nickel(II) bis-(3-thienylacetate).

ABSTRACT: In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa-hedral coordination geometry, defined by six N atoms from the imidazole ligands. Inter-molecular N-H?O hydrogen-bonding inter-actions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774?(1):0.226?(1) and ca 0.753?(5):0.247?(5).

SUBMITTER: Song WD 

PROVIDER: S-EPMC2961043 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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Hexakis(1H-imidazole-κN)nickel(II) bis-(3-thienylacetate).

Song Wen-Dong WD   Ji Li-Li LL   Wang Hao H  

Acta crystallographica. Section E, Structure reports online 20080314 Pt 4

In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa-hedral coordination geometry, defined by six N atoms from the imidazole ligands. Inter-molecular N-H⋯O hydrogen-bonding inter-actions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5). ...[more]

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