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{?-6,6'-Dimeth-oxy-2,2'-[1,2-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenolato}methano-lcopper(II)sodium(I).

ABSTRACT: In the title complex, [NaCu(C(22)H(18)N(2)O(4))Cl(CH(3)OH)], the Cu atom lies nearly in the plane defined by the N(2)O(2) core of donor atoms, the out-of-plane distance being 0.001?(2)?Å. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [maximum displacement from the mean plane through the five atoms = 0.152?(3)?Å for Na]. The crystal structure is stabilized by inter-molecular C-H?Cl and O-H?Cl hydrogen bonds, which link the mol-ecules into dimers. The crystal packing is further stabilized by weak ?-? stacking inter-actions [centroid-centroid distances of 3.442?(4), 3.482?(3), 3.350?(2), 3.531?(4) 3.575?(2) and 3.604?(2)?Å].

SUBMITTER: Bian J

PROVIDER: S-EPMC2961150 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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{μ-6,6'-Dimeth-oxy-2,2'-[1,2-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenolato}methano-lcopper(II)sodium(I).

Bian Jiang J

Acta crystallographica. Section E, Structure reports online 20080404 Pt 5

In the title complex, [NaCu(C(22)H(18)N(2)O(4))Cl(CH(3)OH)], the Cu atom lies nearly in the plane defined by the N(2)O(2) core of donor atoms, the out-of-plane distance being 0.001 (2) Å. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [maximum displacement from the mean plane through the f ...[more]

PMID: 21202180

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