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(S)-(-)-Methyl 2-(p-tolyl-sulfon-yloxy)-propanoate.

ABSTRACT: In the title compound, C(11)H(14)O(5)S, there is an intra-molecular C-H?O hydrogen bond, for which the C-C-S-O torsion angle involving the acceptor and donor atoms is 2.4?(4)°. The dihedral angle between the benzene ring and the methoxy-carbonyl plane is 52.7?(4)°. In the crystal structure, mol-ecules are linked via inter-molecular C-H?O hydrogen bonds, forming a mol-ecular chain along the b axis.

SUBMITTER: Chen W

PROVIDER: S-EPMC2961152 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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(S)-(-)-Methyl 2-(p-tolyl-sulfon-yloxy)-propanoate.

Chen Wei W Liu Shan S Chu Qing-Yan QY Luo Wei W Zhu Hong-Jun HJ

Acta crystallographica. Section E, Structure reports online 20080418 Pt 5

In the title compound, C(11)H(14)O(5)S, there is an intra-molecular C-H⋯O hydrogen bond, for which the C-C-S-O torsion angle involving the acceptor and donor atoms is 2.4 (4)°. The dihedral angle between the benzene ring and the methoxy-carbonyl plane is 52.7 (4)°. In the crystal structure, mol-ecules are linked via inter-molecular C-H⋯O hydrogen bonds, forming a mol-ecular chain along the b axis. ...[more]

PMID: 21202351

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