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N'-(2-Hydr-oxy-5-chloro-benzyl-idene)-4-nitro-benzohydrazide methanol solvate.

ABSTRACT: The title compound, C(14)H(10)ClN(3)O(4)·CH(4)O, was synthesized from the reaction of 5-chloro-salicylaldehyde with 4-nitro-benzohydrazide in methanol. The Schiff base mol-ecule is nearly planar, with a dihedral angle of 9.1?(3)° between the two benzene rings. The methanol solvent mol-ecules are linked to the Schiff base mol-ecules by N-H?O, O-H?N and O-H?O hydrogen bonds, forming chains running parallel to the a axis.

SUBMITTER: Han L

PROVIDER: S-EPMC2961199 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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N'-(2-Hydr-oxy-5-chloro-benzyl-idene)-4-nitro-benzohydrazide methanol solvate.

Han Ling L Huang Shan-Shan SS Huang Qing-Bai QB Zhou Xue-Mei XM Diao Yun-Peng YP

Acta crystallographica. Section E, Structure reports online 20080402 Pt 5

The title compound, C(14)H(10)ClN(3)O(4)·CH(4)O, was synthesized from the reaction of 5-chloro-salicylaldehyde with 4-nitro-benzohydrazide in methanol. The Schiff base mol-ecule is nearly planar, with a dihedral angle of 9.1 (3)° between the two benzene rings. The methanol solvent mol-ecules are linked to the Schiff base mol-ecules by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds, forming chains running parallel to the a axis. ...[more]

PMID: 21202274

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