Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato)cuprate(II) trihydrate.

ABSTRACT: In the title compound, (C(4)H(14)N(2))[Cu(C(7)H(3)NO(4))(2)]·3H(2)O or (bdaH(2))[Cu(pydc)(2)]·3H(2)O (where bda is butane-1,4-diamine and pydcH(2) is pyridine-2,6-dicarboxylic acid), the Cu(II) atom is coordinated by four O atoms [Cu-O = 2.0557?(16)-2.3194?(16)?Å] and two N atoms [Cu-N = 1.9185?(18) and 1.9638?(18)?Å] from two chelating rings of the pydc(2-) anions, which act as tridentate ligands. The geometry of the resulting CuN(2)O(4) coordination can be described as distorted octa-hedral. The the two pydc(2-) fragments are almost perpendicular to one another [77.51?(11)°]. To balance the charges, two centrosymmetric protonated butane-1,4-diammonium, (bdaH(2))(2+) cations are present. In the crystal structure, extensive O-H?O, N-H?O and C-H?O hydrogen bonds [D?A = 2.720?(2)-3.446?(3)?Å], ion pairing, C-O?? [O?? = 3.099?(2)?Å] and ?-? stacking inter-actions between the pydc(2-) rings [centroid-centroid distance = 3.5334?(15)?Å] contribute to the formation of a three-dimensional supra-molecular structure.

SUBMITTER: Aghabozorg H 

PROVIDER: S-EPMC2961264 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature