Ontology highlight
ABSTRACT:
SUBMITTER: Xie B
PROVIDER: S-EPMC2961295 | biostudies-literature | 2008 Apr
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20080404 Pt 5
In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms. The two O,O'-bis-(2-phenyl-meth-yl) dithio-phosphate anions act as counter-ions to balance the charge a ...[more]