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Methyl 4-amino-3-methyl-benzoate.

ABSTRACT: In the mol-ecule of the title compound, C(9)H(11)NO(2), the methyl C and amino N atoms bonded to the benzene ring lie in the ring plane. Intra-molecular C-H?O hydrogen bonding results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 2.73?(3)° with respect to the benzene ring, so they are nearly coplanar. In the crystal structure, inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains elongated along the c axis and stacked along the b axis.

SUBMITTER: Li X

PROVIDER: S-EPMC2961297 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Methyl 4-amino-3-methyl-benzoate.

Li Xiang X Yuan Lian-Shan LS Wang Dan D Liu Shan S Yao Cheng C

Acta crystallographica. Section E, Structure reports online 20080423 Pt 5

In the mol-ecule of the title compound, C(9)H(11)NO(2), the methyl C and amino N atoms bonded to the benzene ring lie in the ring plane. Intra-molecular C-H⋯O hydrogen bonding results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 2.73 (3)° with respect to the benzene ring, so they are nearly coplanar. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains elongated along the c axis and stacked along the b axis. ...[more]

PMID: 21202370

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