Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

5-Chloro-2-methoxy-anilinium nitrate.

ABSTRACT: The title salt, C(7)H(9)ClNO(+)·NO(3) (-), exhibits extensive hydrogen bonding between the ammonium functional group and the nitrate anion. A two-dimensional network of bifurcated N-H?O hydrogen bonds generates corrugated layers in the bc plane. The organic mol-ecules are stacked in a parallel orientation as a result of ?-? inter-actions, with an inter-ring distance of 3.837?Å.

SUBMITTER: Hemissi H

PROVIDER: S-EPMC2961331 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

5-Chloro-2-methoxy-anilinium nitrate.

Hemissi Hanene H Abid Sonia S Rzaigui Mohamed M

Acta crystallographica. Section E, Structure reports online 20080404 Pt 5

The title salt, C(7)H(9)ClNO(+)·NO(3) (-), exhibits extensive hydrogen bonding between the ammonium functional group and the nitrate anion. A two-dimensional network of bifurcated N-H⋯O hydrogen bonds generates corrugated layers in the bc plane. The organic mol-ecules are stacked in a parallel orientation as a result of π-π inter-actions, with an inter-ring distance of 3.837 Å. ...[more]

PMID: 21202293

Similar Datasets

4-Methoxy-anilinium bromide.

Project description:The title compound, C(7)H(10)NO(+)·Br(-), consists of almost planar 4-methoxy-anilinium cations, wherein the O atom lies 0.049?(3)?Å out of the plane formed by the non-H atoms, and a Br(-) anion. Strong N-H?Br and N-H?(Br,Br) hydrogen bonding contributes to the stability of the crystal structure and links the cations and anions into a three-dimensional network.

| S-EPMC2970251 | biostudies-literature

4-Methoxy-anilinium chloride.

Project description:The crystal structure of the title compound, C(7)H(10)NO(+)·Cl(-), was synthesized by the reaction of 4-methoxy-aniline and hydro-chloric acid. In the crystal structure, the ions are involved in inter-molecular N-H?Cl hydrogen bonds.

| S-EPMC2970478 | biostudies-literature

2,5-Dimethyl-anilinium nitrate.

Project description:In the title salt, C(8)H(12)N(+)·NO(3) (-), all non-H atoms of the cation lie on mirror planes. The nitrate counteranion has m symmetry and acts as a hydrogen-bond acceptor of N-H?O hydrogen bonds, connecting the cations and anions into layers running parallel to the ab plane.

| S-EPMC2977111 | biostudies-literature

2-Cyano-anilinium nitrate.

Project description:In the title compound, C(7)H(7)N(2) (+)·NO(3) (-), all atoms of the cation, with the exception of two H atoms of the NH(3) group, lie on a mirror plane, while the anion lies across this plane with the N and one O atom on the mirror plane. In the crystal structure, the organic cations and NO(3) (-) anions are linked by N-H?N and N-H?O hydrogen bonds, forming a two-dimensional network parallel to (100).

| S-EPMC2962190 | biostudies-literature

4-Iodo-anilinium nitrate.

Project description:In the title compound, C(6)H(7)IN(+)·NO(3) (-), ?-? stacking inter-actions [centroid-centroid distances = 4.014?(4) and 4.029?(4)?Å] stabilize the crystal structure and strong N-H?O and N-H?N hydrogen bonds link the cations and anions into zigzag chains running parallel to the c axis. The asymmetric unit contains two unique cations and anions.

| S-EPMC2979466 | biostudies-literature

3-Methyl-anilinium nitrate.

Project description:In the title compound, C(7)H(10)N(+)·NO(3) (-), the 3-methyl-anilinium cations inter-act with the nitrate anions through strong bifurcated N(+)-H?(O,O) hydrogen bonds, forming a two-dimensional hydrogen-bonded network.

| S-EPMC3006795 | biostudies-literature

4-Methyl-anilinium nitrate.

Project description:In the crystal structure of the title compound, C(7)H(10)N(+)·NO(3) (-), N-H⋯O hydrogen bonds involving the ammonium group and the nitrate O atoms result in the formation of zigzag chains propagating in [100].

| S-EPMC2983992 | biostudies-literature

4-Meth-oxy-anilinium nitrate.

Project description:The title compound, C(7)H(10)NO(+)·NO(3) (-), crystallized with two p-ansidinium cations and two nitrate anions in the asymmetric unit. As well as Columbic and van der Waals forces, moleucles inter-act via multiple bifurcated N-H?O hydrogen bonds that help consolidate the crystal packing, resulting in a three-dimensional network.

| S-EPMC3200668 | biostudies-literature

4-Acetamido-anilinium nitrate monohydrate.

Project description:In the title hydrated salt, C(8)H(11)N(2)O(+)·NO(3) (-)·H(2)O, the N-C bond distances [1.349 (2) and 1.413 (2) Å] along with the sum of the angles (359.88°) around the acetamide N atom clearly indicate that the heteroatom has an sp(2) character. The ammonium group is involved in a total of three N-H⋯O hydrogen bonds, two of these are with a water mol-ecule, which forms two O-H⋯O hydrogen bonds. All these hydrogen bonds link the ionic units and the water mol-ecule into infinite planar layers parallel to (100). The remaining two N-H⋯O inter-actions in which the ammoniun group is involved link these layers into an infinite three-dimensional network.

| S-EPMC3379248 | biostudies-literature

4-Chloro-anilinium bromide.

Project description:In the title compound, C(6)H(7)ClN(+)·Br(-), the amino N atom is protonated. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.004?(3)?Å]. In the crystal, N-H?Br hydrogen bonds connect the ions, forming a ribbon-like structure propagating along [010].

| S-EPMC3393291 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data