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{2,2'-[Ethyl-enebis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O'}oxido-vanadium(IV).


ABSTRACT: The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N'-bis-(salicyl-idene)ethyl-enediamine under hydro-thermal conditions. The asymmetric unit contains two mol-ecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C-H?O hydrogen bonds lead to a three-dimensional supra-molecular structure.

SUBMITTER: Wang C 

PROVIDER: S-EPMC2961374 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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{2,2'-[Ethyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}oxido-vanadium(IV).

Wang Cheng C   Yuan Ji-Hong JH   Xie Gang G   Yu Ming-Juan MJ   Li Jing J  

Acta crystallographica. Section E, Structure reports online 20080507 Pt 6


The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N'-bis-(salicyl-idene)ethyl-enediamine under hydro-thermal conditions. The asymmetric unit contains two mol-ecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure. ...[more]

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