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?-Bis(diphenyl-phosphan-yl)borato-?P:P'-bis-[dicarbon-yl(?-cyclo-penta-dien-yl)iron(II)] tetrachloridoferrate(III) chloro-form solvate.

ABSTRACT: The title compound, [Fe(2)(C(5)H(5))(2)(C(24)H(22)BP(2))(CO)(4)][FeCl(4)]·CHCl(3), is an oxidation product of CpFe(CO)(2)PPh(2)BH(3). One pair of phenyl rings attached to the two different P atoms are almost parallel, as are the other pair [dihedral angles = 8.7?(5) and 8.9?(5)°]. The planes of the two cyclo-penta-dienyl rings are inclined by 26.8?(7)° with respect to each other. The carbonyl groups at each Fe atom are almost perpendicular [C-Fe-C = 92.6?(6) and 94.3?(5)°].

SUBMITTER: Dornhaus F

PROVIDER: S-EPMC2961392 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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μ-Bis(diphenyl-phosphan-yl)borato-κP:P'-bis-[dicarbon-yl(η-cyclo-penta-dien-yl)iron(II)] tetrachloridoferrate(III) chloro-form solvate.

Dornhaus Franz F Lerner Hans-Wolfram HW Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20080521 Pt 6

The title compound, [Fe(2)(C(5)H(5))(2)(C(24)H(22)BP(2))(CO)(4)][FeCl(4)]·CHCl(3), is an oxidation product of CpFe(CO)(2)PPh(2)BH(3). One pair of phenyl rings attached to the two different P atoms are almost parallel, as are the other pair [dihedral angles = 8.7 (5) and 8.9 (5)°]. The planes of the two cyclo-penta-dienyl rings are inclined by 26.8 (7)° with respect to each other. The carbonyl groups at each Fe atom are almost perpendicular [C-Fe-C = 92.6 (6) and 94.3 (5)°]. ...[more]

PMID: 21202516

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