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(E)-2-Furyl methyl ketone 2,4-dinitro-phenyl-hydrazone.

ABSTRACT: Crystals of the title compound, C(12)H(10)N(4)O(5), were obtained from a condensation reaction of 2,4-dinitro-phenyl-hydrazine and 2-furyl methyl ketone. The mol-ecule displays a nearly planar structure, and the furan ring is slightly twisted by a dihedral angle of 12.62?(6)° with respect to the phenyl-hydrazone plane. The face-to-face separation of 3.287?(7)?Å between parallel benzene rings of adjacent mol-ecules indicates the existence of ?-? stacking between dinitro-phenyl rings in the crystal structure.

SUBMITTER: Shan S

PROVIDER: S-EPMC2961490 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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(E)-2-Furyl methyl ketone 2,4-dinitro-phenyl-hydrazone.

Shan Shang S Tian Yu-Liang YL Wang Shan-Heng SH Wang Wen-Long WL Xu Ying-Li YL

Acta crystallographica. Section E, Structure reports online 20080524 Pt 6

Crystals of the title compound, C(12)H(10)N(4)O(5), were obtained from a condensation reaction of 2,4-dinitro-phenyl-hydrazine and 2-furyl methyl ketone. The mol-ecule displays a nearly planar structure, and the furan ring is slightly twisted by a dihedral angle of 12.62 (6)° with respect to the phenyl-hydrazone plane. The face-to-face separation of 3.287 (7) Å between parallel benzene rings of adjacent mol-ecules indicates the existence of π-π stacking between dinitro-phenyl rings in the crysta ...[more]

PMID: 21202661

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