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3,3'-Bis(4-nitro-phen-yl)-1,1'-(p-phenyl-ene)dithio-urea dimethyl sulfoxide disolvate.

ABSTRACT: The asymmetric unit of the title compound, C(22)H(16)N(6)O(6)S(2)·2C(2)H(6)OS, consists of one half-mol-ecule of the centrosymmetric thiourea derivative and one molecule of dimethyl sulfoxide (DMSO). The carbonyl group forms an intra-molecular hydrogen bond with the NH group, creating a six-membered (C-N-C-N-H?O) ring. Two other N-H?O hydro-gen bonds link one mol-ecule of the thio-urea to two mol-ecules of DMSO.

SUBMITTER: Dong WK

PROVIDER: S-EPMC2961527 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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3,3'-Bis(4-nitro-phen-yl)-1,1'-(p-phenyl-ene)dithio-urea dimethyl sulfoxide disolvate.

Dong Wen-Kui WK Yan Hai-Bo HB Chai Lan-Qin LQ Lv Zhong-Wu ZW Zhao Chun-Yu CY

Acta crystallographica. Section E, Structure reports online 20080517 Pt 6

The asymmetric unit of the title compound, C(22)H(16)N(6)O(6)S(2)·2C(2)H(6)OS, consists of one half-mol-ecule of the centrosymmetric thiourea derivative and one molecule of dimethyl sulfoxide (DMSO). The carbonyl group forms an intra-molecular hydrogen bond with the NH group, creating a six-membered (C-N-C-N-H⋯O) ring. Two other N-H⋯O hydro-gen bonds link one mol-ecule of the thio-urea to two mol-ecules of DMSO. ...[more]

PMID: 21202611

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