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1-De-oxy-d-arabinitol.

ABSTRACT: Addition of methyl lithium to d-erythrono-1,4-lactone followed by acid deprotection was shown, by X-ray crystallography, to give 1-de-oxy-d-arabinitol, C(5)H(12)O(4), rather than 1-de-oxy-d-ribitol as the major product. The crystal structure exists as hydrogen-bonded chains of mol-ecules running parallel to the c axis which are further linked together by hydrogen bonds. Each mol-ecule is a donor and an acceptor for four hydrogen bonds.

SUBMITTER: Jenkinson SF

PROVIDER: S-EPMC2961547 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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1-De-oxy-d-arabinitol.

Jenkinson Sarah F SF Cruz Filipa P FP Booth Kathrine V KV Fleet George W J GW Izumori Ken K Yu Chu-Yi CY Watkin David J DJ

Acta crystallographica. Section E, Structure reports online 20080507 Pt 6

Addition of methyl lithium to d-erythrono-1,4-lactone followed by acid deprotection was shown, by X-ray crystallography, to give 1-de-oxy-d-arabinitol, C(5)H(12)O(4), rather than 1-de-oxy-d-ribitol as the major product. The crystal structure exists as hydrogen-bonded chains of mol-ecules running parallel to the c axis which are further linked together by hydrogen bonds. Each mol-ecule is a donor and an acceptor for four hydrogen bonds. ...[more]

PMID: 21202536

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