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2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth-yl)mesitylene methanol solvate.

ABSTRACT: In the title compound, C(27)H(27)N(3)O(3)S(3)·CH(4)O, the dihedral angles formed by the mesitylene ring with the three oxopyridyl rings are 89.6?(1), 75.5?(1) and 80.69?(1)°, indicating that all three are nearly perpendicular to the mesitylene ring. Intra-molecular C-H?S hydrogen bonds generate S(6) ring motifs. The crystal structure is stabilized by intra-molecular C-H?S and inter-molecular C-H?O hydrogen bonds and weak C-H?? inter-actions.

SUBMITTER: Ravindran Durai Nayagam B

PROVIDER: S-EPMC2961605 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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2,4,6-Tris(1-oxo-2-pyridylsulfanylmeth-yl)mesitylene methanol solvate.

Ravindran Durai Nayagam B B Jebas Samuel Robinson SR Ravi Samuelraj C C Schollmeyer Dieter D

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

In the title compound, C(27)H(27)N(3)O(3)S(3)·CH(4)O, the dihedral angles formed by the mesitylene ring with the three oxopyridyl rings are 89.6 (1), 75.5 (1) and 80.69 (1)°, indicating that all three are nearly perpendicular to the mesitylene ring. Intra-molecular C-H⋯S hydrogen bonds generate S(6) ring motifs. The crystal structure is stabilized by intra-molecular C-H⋯S and inter-molecular C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions. ...[more]

PMID: 21202559

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