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Trans-Diazido-(1,8-dibenzyl-1,3,6,8,10,13-hexa-azacyclo-tetra-deca-ne)nickel(II).

ABSTRACT: In the centrosymmetric title compound, [Ni(N(3))(2)(C(22)H(34)N(6))], the Ni(II) ion is coordinated by the four secondary N atoms of the macrocyclic ligand in a square-planar fashion with two N atoms of the azide ions in axial positions, resulting in a tetra-gonally distorted octa-hedron. An N-H?N hydrogen-bonding inter-action between the secondary amine N atom of the macrocycle and an adjacent azide ion gives rise to a chain structure.

SUBMITTER: Shin JW

PROVIDER: S-EPMC2961652 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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trans-Diazido-(1,8-dibenzyl-1,3,6,8,10,13-hexa-azacyclo-tetra-deca-ne)nickel(II).

Shin Jong Won JW Min Kil Sik KS

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7

In the centrosymmetric title compound, [Ni(N(3))(2)(C(22)H(34)N(6))], the Ni(II) ion is coordinated by the four secondary N atoms of the macrocyclic ligand in a square-planar fashion with two N atoms of the azide ions in axial positions, resulting in a tetra-gonally distorted octa-hedron. An N-H⋯N hydrogen-bonding inter-action between the secondary amine N atom of the macrocycle and an adjacent azide ion gives rise to a chain structure. ...[more]

PMID: 21202794

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