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Chloridobis{N-[(dimethyl-amino)dimethyl-silyl]-2,6-dimethyl-anilido-?N,N'}iron(III).

ABSTRACT: The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N'-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe-N(amino) bond is longer than the Fe-N(anilide) bond by about 0.37?Å. The mol-ecule displays a pseudo-twofold rotation. The five-coordinate Fe atom demonstrates a highly distorted trigonal-bipyramidal geometry.

SUBMITTER: Chen J

PROVIDER: S-EPMC2961661 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Chloridobis{N-[(dimethyl-amino)dimethyl-silyl]-2,6-dimethyl-anilido-κN,N'}iron(III).

Chen Juan J

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7

The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N'-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe-N(amino) bond is longer than the Fe-N(anilide) bond by about 0.37 Å. The mol-ecule displays a pseudo-twofold rotation. The five-coordinate Fe atom demonstrates a highly distorted trigonal-bipyramidal geometry. ...[more]

PMID: 21202791

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