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1,4-Bis(4-pyridylsulfanylmeth-yl)benzene.

ABSTRACT: In the title compound, C(18)H(16)N(2)S(2), a crystallographic inversion centre lies at the centre of the benzene ring, and the two terminal 4-mercaptopyridyl groups adopt an anti geometry. Each benzene ring makes a dihedral angle of 55.4?(1)° with the plane of the benzene fragment. The crystal structure is stabilized by C-H?? inter-actions between a benzene H atom and a pyridyl ring of a neighbouring mol-ecule. In addition, the crystal structure exhibits inter-molecular C-H?N inter-actions.

SUBMITTER: Moon SH

PROVIDER: S-EPMC2961669 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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1,4-Bis(4-pyridylsulfanylmeth-yl)benzene.

Moon Suk-Hee SH Park Ki-Min KM

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7

In the title compound, C(18)H(16)N(2)S(2), a crystallographic inversion centre lies at the centre of the benzene ring, and the two terminal 4-mercaptopyridyl groups adopt an anti geometry. Each benzene ring makes a dihedral angle of 55.4 (1)° with the plane of the benzene fragment. The crystal structure is stabilized by C-H⋯π inter-actions between a benzene H atom and a pyridyl ring of a neighbouring mol-ecule. In addition, the crystal structure exhibits inter-molecular C-H⋯N inter-actions. ...[more]

PMID: 21202916

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