Unknown

Dataset Information

0

Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-?N)picolinato-?N,O]manganese(II) bis-(3,5-dinitro-benzoic acid) solvate.

ABSTRACT: In the title complex, [Mn(C(11)H(10)N(3)O(2))(2)]·2C(7)H(4)N(2)O(6), the Mn(II) atom has a disorted octa-hedral coordination formed by four N and two O atoms of two mer-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands (DMPP). Each of the two symmetry-independent 3,5-dinitro-benzoic acid mol-ecules is linked to the mol-ecule of the complex via a hydrogen bond involving its carboxylic H atom and one of the DMPP ligands of the complex. However, in one of the DMPP ligands, the non-coordinated carbonyl O atom serves as the hydrogen-bond acceptor, whereas in the second ligand it is the Mn-coordinated O atom which is involved in the hydrogen bonding.

SUBMITTER: Hu FL 

PROVIDER: S-EPMC2961712 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN)picolinato-κN,O]manganese(II) bis-(3,5-dinitro-benzoic acid) solvate.

Hu Fei-Long FL   Yin Xian-Hong XH   Luo Wei-Qiang WQ   Zhao Kai K   Lin Cui-Wu CW  

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the title complex, [Mn(C(11)H(10)N(3)O(2))(2)]·2C(7)H(4)N(2)O(6), the Mn(II) atom has a disorted octa-hedral coordination formed by four N and two O atoms of two mer-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands (DMPP). Each of the two symmetry-independent 3,5-dinitro-benzoic acid mol-ecules is linked to the mol-ecule of the complex via a hydrogen bond involving its carboxylic H atom and one of the DMPP ligands of the complex. However, in one of the DMPP ligands, the non-coordinated carb  ...[more]

Similar Datasets

Unknown Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]manganese(II) trihydrate.
| S-EPMC2914962 | biostudies-literature
Unknown Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II) tetra-hydrate.
| S-EPMC2914946 | biostudies-literature
Unknown Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κN,O]cadmium(II) 1.75-hydrate.
| S-EPMC2960373 | biostudies-literature
Unknown Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)-aqua-[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithio-cyanato-nickel(II) (1/1).
| S-EPMC2914961 | biostudies-literature
Unknown Bis{4-[(3,5-dimethyl-1H-pyrazol-4-yl)selan-yl]-3,5-dimethyl-1H-pyrazol-2-ium} chloride monohydrate.
| S-EPMC3393332 | biostudies-literature
Unknown Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-?O,N,N']copper(II) tetra-hydrate.
| S-EPMC2960233 | biostudies-literature
Unknown Diaqua-bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-?N,N',O](nitrato-?O,O')lanthanum(III) monohydrate.
| S-EPMC2960405 | biostudies-literature
Unknown Bis[bis-(3,5-dimethyl-1H-pyrazol-1-yl)-borato]cobalt(II).
| S-EPMC3151970 | biostudies-literature
Unknown [6-(3,5-Dimethyl-1H-pyrazol-1-yl)picolinato](pyridine-2,6-dicarboxyl-ato)copper(II) dihydrate.
| S-EPMC2961460 | biostudies-literature
Unknown Dichlorido(3,5-dimethyl-1H-pyrazole-κN)[hydro-tris-(3,5-dimethyl-1H-pyrazol-1-yl-κN)borato]chromium(III) tetra-hydro-furan mono-solvate.
| S-EPMC3051926 | biostudies-literature