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2-Amino-N-(2-hydr-oxy-3-methoxy-benzyl-idene)aniline.

ABSTRACT: In the title compound, C(14)H(14)N(2)O(2), the dihedral angle between the two benzene rings is 9.67?(10)°. Two intra-molecular O-H?N and N-H?N hydrogen bonds involving the hydr-oxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, N-H?O hydrogen bonds link neighboring mol-ecules. Mol-ecules are also stacked in a head-to-tail fashion along the c axis through ?-? inter-actions [centroid-centroid separation of 3.7357?(12)?Å] and are further linked by weak inter-molecular C-H?? inter-actions, giving a zigzag arrangement along the b axis.

SUBMITTER: Al-Douh MH

PROVIDER: S-EPMC2961787 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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2-Amino-N-(2-hydr-oxy-3-methoxy-benzyl-idene)aniline.

Al-Douh Mohammed H MH Hamid Shafida A SA Osman Hasnah H Kia Reza R Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the title compound, C(14)H(14)N(2)O(2), the dihedral angle between the two benzene rings is 9.67 (10)°. Two intra-molecular O-H⋯N and N-H⋯N hydrogen bonds involving the hydr-oxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, N-H⋯O hydrogen bonds link neighboring mol-ecules. Mol-ecules are also stacked in a head-to-tail fashion along the c axis through π-π inter-actions [centroid-centroid separation of 3.7357 (12) Å] and are further linked by weak ...[more]

PMID: 21202842

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