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Catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κN:N'].

ABSTRACT: In the title compound, [CoCl(2)(C(13)H(14)N(2))](n), 1,3-bis-(4-pyrid-yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is bis-ected through the central C atom in the chain by a second mirror plane. There are some π-π stacking inter-ations in the crystal structure, with inter-planar distances of 3.449 Å, which are responsible for the supra-molecular assembly.

SUBMITTER: Xu W

PROVIDER: S-EPMC2961947 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κN:N'].

Xu Wei W Lin Jian-Li JL

Acta crystallographica. Section E, Structure reports online 20080712 Pt 8

In the title compound, [CoCl(2)(C(13)H(14)N(2))](n), 1,3-bis-(4-pyrid-yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is bis-ected through the central C atom in the chain by a second mirror plane. There are some π-π stacking inter-ations in the crystal structure, with inter-planar distances of 3.449 Å, which are respons ...[more]

PMID: 21203017

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