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[μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl-pyrazol-1-yl)-2λ,4λ,6λ-1,3,5,2,4,6-triaza-triphosphinine]tris-[cis-dichloridopalladium(II)].

ABSTRACT: The title complex, [Pd(3)Cl(6)(C(30)H(42)N(15)P(3))], possesses C(3) mol-ecular symmetry. The P and N atoms of the cyclo-triphosphazene and the Pd atom are located on the crystallographic mirror plane. Each of the three symmetry-related Pd atoms is coordinated by two chloride ligands and two exocyclic pyrazolyl N atoms, but not by the cyclo-triphosphazene N atoms.

SUBMITTER: Yun SY

PROVIDER: S-EPMC2961992 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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[μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl-pyrazol-1-yl)-2λ,4λ,6λ-1,3,5,2,4,6-triaza-triphosphinine]tris-[cis-dichloridopalladium(II)].

Yun Sung Yol SY Lee Soon W SW

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

The title complex, [Pd(3)Cl(6)(C(30)H(42)N(15)P(3))], possesses C(3) mol-ecular symmetry. The P and N atoms of the cyclo-triphosphazene and the Pd atom are located on the crystallographic mirror plane. Each of the three symmetry-related Pd atoms is coordinated by two chloride ligands and two exocyclic pyrazolyl N atoms, but not by the cyclo-triphosphazene N atoms. ...[more]

PMID: 21203062

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[μ-2,2,4,4,6,6-Hexakis(3,5-dimethyl-pyrazol-1-yl)-2λ,4λ,6λ-1,3,5,2,4,6-triaza-triphosphinine]bis-[bis-(nitrato- κO,O')cadmium(II)].

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