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Bis{(E)-2-eth-oxy-6-[2-(ethyl-ammonio)ethyl-iminometh-yl]phenolato}nickel(II) bis(perchlorate).

ABSTRACT: In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H?O hydrogen bonds, forming chains running along the a axis.

SUBMITTER: Zhu XW

PROVIDER: S-EPMC2962001 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Bis{(E)-2-eth-oxy-6-[2-(ethyl-ammonio)ethyl-iminometh-yl]phenolato}nickel(II) bis(perchlorate).

Zhu Xue-Wen XW Yang Xu-Zhao XZ

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the a axis. ...[more]

PMID: 21203071

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