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1-[2-(2,6-Dichloro-benz-yloxy)-2-(2-fur-yl)eth-yl]-1H-benzimidazole.

ABSTRACT: In the mol-ecule of the title compound, C(20)H(16)Cl(2)N(2)O(2), the planar benzimidazole ring system is oriented with respect to the furan and dichloro-benzene rings at dihedral angles of 53.39?(6) and 31.04?(5)°, respectively. In the crystal structure, inter-molecular C-H?Cl hydrogen bonds link the mol-ecules into centrosymmetric R(2) (2)(8) dimers. These dimers are connected via a C-H?? contact between the benzimidazole and the furan rings, and ?-? contacts between the benz-imidazole and dichloro-benzene ring systems [centroid-centroid distances = 3.505?(1), 3.567?(1), 3.505?(1) and 3.567?(1)?Å].

SUBMITTER: Ozel Guven O

PROVIDER: S-EPMC2962068 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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1-[2-(2,6-Dichloro-benz-yloxy)-2-(2-fur-yl)eth-yl]-1H-benzimidazole.

Ozel Güven Ozden O Erdoğan Taner T Coles Simon J SJ Hökelek Tuncer T

Acta crystallographica. Section E, Structure reports online 20080709 Pt 8

In the mol-ecule of the title compound, C(20)H(16)Cl(2)N(2)O(2), the planar benzimidazole ring system is oriented with respect to the furan and dichloro-benzene rings at dihedral angles of 53.39 (6) and 31.04 (5)°, respectively. In the crystal structure, inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric R(2) (2)(8) dimers. These dimers are connected via a C-H⋯π contact between the benzimidazole and the furan rings, and π-π contacts between the benz-imidazole and dich ...[more]

PMID: 21203152

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