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2,2'-Dichloro-1,1'-[(propane-1,3-diyldi-oxy)bis-(nitrilo-methyl-idyne)]dibenzene.

ABSTRACT: The title compound, C(17)H(16)Cl(2)N(2)O(2), assumes a V-shape configuration with a dihedral angle between the two halves of the mol-ecule of 79.60?(4)°. The asymmetric unit comprises one half-mol-ecule with a crystallographic twofold rotation axis passing through the central C atom. There are weak inter-molecular ?-? stacking inter-actions between neighbouring benzene rings with inter-molecular plane-to-plane distances of 3.277?(6) and 3.465?(5)?Å along the a and c axes, respectively. In the crystal structure, weak inter-molecular C-H?O bonds link each mol-ecule to four others to form an infinite three-dimensional network.

SUBMITTER: He XN

PROVIDER: S-EPMC2962157 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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2,2'-Dichloro-1,1'-[(propane-1,3-diyldi-oxy)bis-(nitrilo-methyl-idyne)]dibenzene.

He Xue-Ni XN Dong Wen-Kui WK Bai Wen-Juan WJ Yan Hai-Bo HB Lv Zhong-Wu ZW

Acta crystallographica. Section E, Structure reports online 20080719 Pt 8

The title compound, C(17)H(16)Cl(2)N(2)O(2), assumes a V-shape configuration with a dihedral angle between the two halves of the mol-ecule of 79.60 (4)°. The asymmetric unit comprises one half-mol-ecule with a crystallographic twofold rotation axis passing through the central C atom. There are weak inter-molecular π-π stacking inter-actions between neighbouring benzene rings with inter-molecular plane-to-plane distances of 3.277 (6) and 3.465 (5) Å along the a and c axes, respectively. In the cr ...[more]

PMID: 21203237

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