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9-Ethyl-10-methyl-acridinium trifluoro-methane-sulfonate.

ABSTRACT: In the mol-ecule of the title compound, C(16)H(16)N(+)·CF(3)SO(3) (-), the central ring adopts a flattened-boat conformation, and the two aromatic rings are oriented at a dihedral angle of 3.94 (2)°. In the crystal structure, weak inter-molecular hydrogen bonds link the mol-ecules. There are π-π contacts between the aromatic rings and the central ring and one of the aromatic rings [centroid-centroid distances = 3.874 (2), 3.945 (2) and 3.814 (2) Å]. There is also an S-O⋯π contact between the central ring and one of the O atoms of the anion.

SUBMITTER: Zadykowicz B

PROVIDER: S-EPMC2967949 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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9-Ethyl-10-methyl-acridinium trifluoro-methane-sulfonate.

Zadykowicz Beata B Wera Michał M Sikorski Artur A Błażejowski Jerzy J

Acta crystallographica. Section E, Structure reports online 20081206 Pt 1

In the mol-ecule of the title compound, C(16)H(16)N(+)·CF(3)SO(3) (-), the central ring adopts a flattened-boat conformation, and the two aromatic rings are oriented at a dihedral angle of 3.94 (2)°. In the crystal structure, weak inter-molecular hydrogen bonds link the mol-ecules. There are π-π contacts between the aromatic rings and the central ring and one of the aromatic rings [centroid-centroid distances = 3.874 (2), 3.945 (2) and 3.814 (2) Å]. There is also an S-O⋯π contact between the cen ...[more]

PMID: 21581674

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