Unknown

Dataset Information

0

1-(3-Chloro-phen-yl)-3-(1-p-tolyl-imidazolidin-2-yl-idene)urea.

ABSTRACT: In the crystal structure of the title compound, C(17)H(17)ClN(4)O, the existence of only one 2-imino-oxo of the five possible N-amino-imino/O-keto-hydr-oxy tautomers is observed and the dihedral angle between the aromatic rings is 29.78 (11)°. The mol-ecular conformation is stabilized by intra-molecular C-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds, in each case generating a six-membered ring. In the crystal structure, the glide-plane-related mol-ecules are linked into C(4) amide chains by inter-molecular N-H⋯O hydrogen bonds, and an inter-molecular C-H⋯O link also occurs.

SUBMITTER: Wysocki W 

PROVIDER: S-EPMC2967957 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

1-(3-Chloro-phen-yl)-3-(1-p-tolyl-imidazolidin-2-yl-idene)urea.

Wysocki Waldemar W   Matosiuk Dariusz D   Karczmarzyk Zbigniew Z   Fidecka Sylwia S   Fruziński Andrzej A  

Acta crystallographica. Section E, Structure reports online 20081206 Pt 1

In the crystal structure of the title compound, C(17)H(17)ClN(4)O, the existence of only one 2-imino-oxo of the five possible N-amino-imino/O-keto-hydr-oxy tautomers is observed and the dihedral angle between the aromatic rings is 29.78 (11)°. The mol-ecular conformation is stabilized by intra-molecular C-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds, in each case generating a six-membered ring. In the crystal structure, the glide-plane-related mol-ecules are linked into C(4) amide chains by inter-molecul  ...[more]

Similar Datasets

Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)imidazolidin-2-yl-idene.
| S-EPMC3007848 | biostudies-literature
Unknown 1-{2-[(4-Chloro-benzyl-idene)amino]phen-yl}-3-phenyl-thio-urea.
| S-EPMC3295530 | biostudies-literature
Unknown {5-Chloro-2-[(4-chloro-benzyl-idene)-amino]-phen-yl}(phen-yl)methanone.
| S-EPMC3295436 | biostudies-literature
Unknown 1-(3-Chloro-phen-yl)-3-(4-nitro-phen-yl)urea.
| S-EPMC3009072 | biostudies-literature
Unknown 1-(3-Chloro-phen-yl)thio-urea.
| S-EPMC3414341 | biostudies-literature
Unknown (Z)-2-Sulfanyl-idene-5-(thio-phen-2-yl-methyl-idene)imidazolidin-4-one.
| S-EPMC3200739 | biostudies-literature
Unknown 1-(4-Chloro-butano-yl)-3-(3-chloro-phen-yl)thio-urea.
| S-EPMC4051110 | biostudies-literature
Unknown 1-(4-Chloro-butano-yl)-3-(2-chloro-phen-yl)thio-urea.
| S-EPMC3344638 | biostudies-literature
Unknown (Z)-4-Chloro-N-(1-{2-[3-(4-chloro-benzoyl)ureido]eth-yl}imidazolidin-2-yl-idene)benzamide.
| S-EPMC3394018 | biostudies-literature
Unknown N,N'-Bis(4-chloro-phen-yl)urea.
| S-EPMC2961192 | biostudies-literature