Ontology highlight
ABSTRACT:
SUBMITTER: Jenkinson SF
PROVIDER: S-EPMC2968166 | biostudies-literature | 2009 Jan
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090108 Pt 2
The reaction of 5-azido-5-de-oxy-2,3-O-isopropyl-idene-2-C-methyl-d-ribose with N,N-diethyl-2-(dimethyl-sulfuranyl-idene)acetamide gave the title compound, C(15)H(26)N(4)O(5), as the major product arising from initial formation of an epoxide which was subsequently opened by intra-molecular attack of the free 4-hydroxyl group. X-ray crystallography confirmed the relative stereochemistry of the title compound and the absolute configuration was determined by the use of d-ribose as the starting mate ...[more]