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Diaqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O'}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate.

ABSTRACT: In the cation of the title compound, [Mn(C(18)H(18)N(2)O(4))(H(2)O)(2)]ClO(4)·0.5C(12)H(24)O(6)·H(2)O, the Mn(III) ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]di-phenolate ligand, completing a distorted octa-hedral geometry. One O atom of the 18-crown-6-ether is disordered over two positions with occupancies of 0.70?(2) and 0.30?(2).

SUBMITTER: Li ZX

PROVIDER: S-EPMC2968196 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Diaqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate.

Li Zhan-Xian ZX Li Xia X Zhang Li-Feng LF Yu Ming-Ming MM

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

In the cation of the title compound, [Mn(C(18)H(18)N(2)O(4))(H(2)O)(2)]ClO(4)·0.5C(12)H(24)O(6)·H(2)O, the Mn(III) ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]di-phenolate ligand, completing a distorted octa-hedral geometry. One O atom of the 18-crown-6-ether is disordered over two positions with occupancies of 0.70 (2) and 0.30 (2). ...[more]

PMID: 21581765

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