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Bis(2,2'-bipyridine-?N,N')dichlorido-platinum(IV) dichloride monohydrate.

ABSTRACT: In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa-hedral environment by four N atoms from the two 2,2'-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt-N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays inter-molecular hydrogen bonding between the water mol-ecule and the Cl anions. There are inter-molecular ?-? inter-actions between adjacent pyridine rings, with a centroid-centroid distance of 3.962?Å.

SUBMITTER: Kim NH

PROVIDER: S-EPMC2968269 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Bis(2,2'-bipyridine-κN,N')dichlorido-platinum(IV) dichloride monohydrate.

Kim Nam-Ho NH Hwang In-Chul IC Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20090114 Pt 2

In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa-hedral environment by four N atoms from the two 2,2'-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt-N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays inter-molecular hydrogen bonding between the water mol-ecule and the Cl anions. There are inter-molecular π-π inter ...[more]

PMID: 21581784

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