Ontology highlight
ABSTRACT:
SUBMITTER: Shin JW
PROVIDER: S-EPMC2968297 | biostudies-literature | 2009 Jan
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090128 Pt 2
The title compound, [Ni(NCS)(2)(C(24)H(38)N(6))], is a thio-cyanate-coordinated aza-macrocyclic nickel(II) complex. There are two independent mol-ecules in the asymmetric unit and their bond lengths and angles are similar. Both Ni atoms have a tetra-gonally distorted octa-hedral geometry, in which the Ni(II) ion is coordinated by the four secondary N atoms of the aza-macrocyclic ligand and by two N atoms of the thio-cyanate ions. The average equatorial Ni-N bond lengths are shorter than the aver ...[more]