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(3RS)-S-[1-(3-Chloro-phen-yl)-2-oxopyr-roli-din-3-yl]thio-uronium bromide.

ABSTRACT: In the title molecular salt, C(11)H(13)ClN(3)OS(+)·Br(-), the C-N bond lengths in the -S-C(NH(2))(2) fragment indicate partial double-bond character of these bonds. The constituent ions are connected by N-H?Br bridges into Z-shaped chains. The supra-molecular architecture of the structure can be described by being composed of these chains inter-locked by additional C-H?Br short contacts. An intra-molecular N-H?O=C bridge, as well as weak C-H?O hydrogen bonds, are also present in the structure.

SUBMITTER: Hanusek J 

PROVIDER: S-EPMC2968325 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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(3RS)-S-[1-(3-Chloro-phen-yl)-2-oxopyr-roli-din-3-yl]thio-uronium bromide.

Hanusek Jiří J   Sedlák Miloš M   Drabina Pavel P   Ružička Aleš A  

Acta crystallographica. Section E, Structure reports online 20090128 Pt 2

In the title molecular salt, C(11)H(13)ClN(3)OS(+)·Br(-), the C-N bond lengths in the -S-C(NH(2))(2) fragment indicate partial double-bond character of these bonds. The constituent ions are connected by N-H⋯Br bridges into Z-shaped chains. The supra-molecular architecture of the structure can be described by being composed of these chains inter-locked by additional C-H⋯Br short contacts. An intra-molecular N-H⋯O=C bridge, as well as weak C-H⋯O hydrogen bonds, are also present in the structure. ...[more]

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