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Chloridobis[diphenyl-glyoximato(1-)-?N,N'](1H-imidazole-?N)cobalt(III) hemihydrate.

ABSTRACT: The Co centre in the title compound, [Co(C(14)H(11)N(2)O(2))(2)Cl(C(3)H(4)N(2))]·0.5H(2)O, shows a slightly distorted octa-hedral coordination geometry. The glyoximate units of the mol-ecule are linked by O-H?O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through inter-molecular N-H?O, N-H?N and O-H?Cl hydrogen bonds. The uncoordinated water mol-ecule shows half-occupation.

SUBMITTER: Meera P

PROVIDER: S-EPMC2968413 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Chloridobis[diphenyl-glyoximato(1-)-κN,N'](1H-imidazole-κN)cobalt(III) hemihydrate.

Meera P P Revathi C C Dayalan A A

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

The Co centre in the title compound, [Co(C(14)H(11)N(2)O(2))(2)Cl(C(3)H(4)N(2))]·0.5H(2)O, shows a slightly distorted octa-hedral coordination geometry. The glyoximate units of the mol-ecule are linked by O-H⋯O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through inter-molecular N-H⋯O, N-H⋯N and O-H⋯Cl hydrogen bonds. The uncoordinated water mol-ecule shows half-occupation. ...[more]

PMID: 21581756

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