Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Poly[dichloridobis(?(2)-di-4-pyridyl sulfide-?N,N')cobalt(II)].

ABSTRACT: In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa-hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra-molecular C-H?N and C-H?Cl hydrogen bonds.

SUBMITTER: Wang JG

PROVIDER: S-EPMC2968483 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κN,N')cobalt(II)].

Wang Jian-Ge JG Qin Jian-Hua JH Zhang Gui-Ying GY

Acta crystallographica. Section E, Structure reports online 20090204 Pt 3

In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa-hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra-molecular C-H⋯N and C-H⋯Cl hydrog ...[more]

PMID: 21582041

Similar Datasets

Aqua-dicrotonato(di-2-pyridyl-amine)cobalt(II).

Project description:The Co atom in the title complex, [Co(CH(3)CHCHCOO)(2)(C(10)H(9)N(3))(H(2)O)], has a distorted recta-ngular-pyramidal geometry formed by the chelating dipyridylamine ligand, and two O atoms of monodentate carboxyl-ate groups of two different crotonate anions and a water molecule. The complex forms a three-dimensional supra-molecular network via inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen-bonding contacts.

| S-EPMC2961059 | biostudies-literature

Dibromido(di-2-pyridyl sulfide-κN,N')zinc(II).

Project description:The molecule of the title compound, [ZnBr(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring in a boat conformation in which the Zn atom is coordinated by two Br atoms and by the two pyridyl N atoms of a single di-2-pyridyl sulfide (dps) ligand within a slightly distorted tetra-hedron. The dihedral angle between the pyridine rings is 52.7 (1)°. As is usual for this type of complex, the sulfide group does not participate in the zinc coordination.

| S-EPMC2960344 | biostudies-literature

Poly[dichloridobis[μ-1-(4-pyridyl-meth-yl)-1,2,4-triazole]cadmium(II)].

Project description:In the title coordination polymer, [CdCl(2)(C(8)H(8)N(4))(2)](n), the Cd(II) atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridyl-meth-yl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl(2)N(4) octa-hedral arrangement. The bridg-ing pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 4(4) sheet parallel to (02). π-π inter-actions between the triazole rings [centroid-centroid distance = 3.428 (2) Å] connect the sheets.

| S-EPMC2983120 | biostudies-literature

(Di-2-pyridyl sulfide-?N,N')diiodidozinc(II).

Project description:The title compound, [ZnI(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring adopting a boat conformation in which the Zn atom is coordinated by two iodide ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand within a slightly distorted tetra-hedron. The Zn, S and I atoms are located on a crystallographic mirror plane. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 60.1?(1)°.

| S-EPMC2914904 | biostudies-other

cis-Dichloridobis(di-2-pyridyl-amine-?N,N')manganese(II).

Project description:In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octa-hedral environment defined by four N atoms of two chelating di-2-pyridyl-amine (dpa) ligands and two Cl(-) anions. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.3?(2) and 30.9?(2)°. The complex mol-ecules are stacked in columns along the c axis and are connected by inter-molecular N-H?Cl hydrogen bonds, forming a three-dimensional network. Weak inter- and intra-molecular ?-? inter-actions are present between the pyridine rings, the shortest centroid-centroid distance being 4.406?(3)?Å.

| S-EPMC3254314 | biostudies-other

Dichlorido(di-2-pyridyl sulfide-?N,N')zinc(II).

Project description:The crystal structure of the title compound, [ZnCl(2)(C(10)H(8)N(2)S)], consists of a six-membered chelate ring in which the Zn atom is approximately tetra-hedrally coordinated by two chloride ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 50.4 (1)°.

| S-EPMC2914903 | biostudies-other

catena-Poly[[diiodidocadmium(II)]-?-4,4'-di-4-pyridyl-2,2'-disulfanediyldipyrimidine].

Project description:In the title compound, [CdI(2)(C(18)H(12)N(6)S(2))](n), the 4,4'-di-4-pyridyl-2,2'-disulfanediyldipyrimidine (L) ligand bridges two Cd(II) centers, forming polymeric zigzag chains extending along the b axis. The Cd(II) ions are coordinated by two N atoms from two L ligands and two iodide anions in a distorted tetra-hedral geometry.

| S-EPMC2980057 | biostudies-literature

Poly[di-?(9)-citrato-cobalt(II)tetra-sodium].

Project description:The title compound, [CoNa(4)(C(6)H(5)O(7))(2)](n), was obtained under hydro-thermal conditions as a minor product. The Co(2+) cation is located on a crystallographic inversion center and is coordinated by six O atoms from two different citrate units, forming a [Co(C(6)H(5)O(7))(2)](4-) building unit with Co-O bond lengths between 2.0578?(17) and 2.0813?(16)?Å. The structure features two crystallographically independent Na(+) ions. The first Na(+) cation is five-coordinated by O atoms of five carboxylate groups from four different citrate anions. The second Na(+) cation is surrounded by six O atoms of five carboxylate groups from five different citrate anions. The carboxylate groups of the citrate are completely depronona-ted, the hydroxyl group, however, is not. It is coordinated to the Co(2+) cation, and through an O-H?O hydrogen bond connected to a neighboring [Co(C(6)H(5)O(7))(2)](4-) building unit. The coordination modes of the carboxyl-ate O atoms vary, with one O atom being coordinated to three different Na(+) cations, three are bridging O atoms bound to two Na(+) cations and two are connected to a Co(2+) cation and a Na(+) cation, respectively. Through these inter-connections, the basic [Co(C(6)H(5)O(7))(2)](4-) building units are linked with each other through coordination of their carboxyl-ate groups to the Na(+) cations, forming a three-dimensional framework.

| S-EPMC3344400 | biostudies-literature

Poly[di-?-aqua-diaqua-di-?(6)-malonato-cobalt(II)dipotassium(I)].

Project description:In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water mol-ecule are located on a mirror plane, and the malonate and one water mol-ecule are located on a twofold rotation axis. The K(I) atom is seven-coordinated by four carboxyl-ate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co(II) atom is in an almost octa-hedral environment formed by four carboxyl-ate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20[Formula: see text]) built up from edge-sharing KO(7) and CoO(6) polyhedra, which are connected by O-H?O hydrogen bonding including water mol-ecules into a three-dimensional network.

| S-EPMC3089327 | biostudies-literature

Tetra-aqua-bis(3,5-di-4-pyridyl-1,2,4-triazolato-κN)cobalt(II) dihydrate.

Project description:The Co(II) atom in the title compound, [Co(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, lies on a center of inversion and is bonded to two N-heterocycles and to four water mol-ecules in a slightly distorted octahedral coordination. The coordinated and lattice water mol-ecules inter-act with the N-heterocycles through O-H⋯N hydrogen bonds, generating a three-dimensional supra-molecular architecture.

| S-EPMC2977553 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data