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[N,N'-Bis(4-bromo-benzyl-idene)-2,2-di-methyl-propane-?N,N']iodidocopper(I).

ABSTRACT: The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7?(3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter-planar angle between the benzene rings is 74.85?(19)°. The crystal structure exhibits weak inter-molecular C-H?? inter-actions, which link the mol-ecules into chains along the b axis.

SUBMITTER: Kia R

PROVIDER: S-EPMC2968488 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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[N,N'-Bis(4-bromo-benzyl-idene)-2,2-di-methyl-propane-κN,N']iodidocopper(I).

Kia Reza R Fun Hoong-Kun HK Kargar Hadi H

Acta crystallographica. Section E, Structure reports online 20090218 Pt 3

The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter-planar angle between the benzene rings is 74.85 (19)°. The crystal structure ...[more]

PMID: 21582073

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