Unknown

Dataset Information

0

[N,N'-Bis(4-bromo-benzyl-idene)-2,2-di-methyl-propane-?N,N']iodidocopper(I).


ABSTRACT: The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7?(3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter-planar angle between the benzene rings is 74.85?(19)°. The crystal structure exhibits weak inter-molecular C-H?? inter-actions, which link the mol-ecules into chains along the b axis.

SUBMITTER: Kia R 

PROVIDER: S-EPMC2968488 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

altmetric image

Publications

[N,N'-Bis(4-bromo-benzyl-idene)-2,2-di-methyl-propane-κN,N']iodidocopper(I).

Kia Reza R   Fun Hoong-Kun HK   Kargar Hadi H  

Acta crystallographica. Section E, Structure reports online 20090218 Pt 3


The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter-planar angle between the benzene rings is 74.85 (19)°. The crystal structure  ...[more]

Similar Datasets

| S-EPMC2968840 | biostudies-literature
| S-EPMC3297910 | biostudies-literature
| S-EPMC3790441 | biostudies-literature
| S-EPMC7534255 | biostudies-literature
| S-EPMC2968300 | biostudies-literature
| S-EPMC2960008 | biostudies-literature
| S-EPMC2960098 | biostudies-literature
| S-EPMC2959888 | biostudies-literature
| S-EPMC2961957 | biostudies-literature
| S-EPMC3008013 | biostudies-literature